High-Pressure Behavior of Silver Fluorides up to 40 GPa

Adam Grzelak, Jakub Gawraczyński, Tomasz Jaroń, Dominik Kurzydłowski, Armand Budzianowski, Zoran Mazej, Piotr J. Leszczyński, Vitali B. Prakapenka, Mariana Derzsi, Viktor V. Struzhkin, Wojciech Grochala

INORGANIC CHEMISTRY, 
Volume 56, Issue 23, 4 December 2017, Pages 14651-14661
DOI: 10.1021/acs.inorgchem.7b02528

Synopsis

AgF2 with its Jahn−Teller-active Ag2+ cation undergoes pressure-induced phase transitions to unprecedented Pca21 and Pbcn polymorphs, not found for other metal difluorides (such as the CdF2 compared here).

Abstract

A combined experimental–theoretical study of silver(I) and silver(II) fluorides under high pressure is reported. For AgI, the CsCl-type structure is stable to at least 39 GPa; the overtone of the IR-active mode is seen in the Raman spectrum. Its AgIIF2 sibling is a unique compound in many ways: it is more covalent than other known difluorides, crystallizes in a layered structure, and is enormously reactive. Using X-ray diffraction and guided by theoretical calculations (density functional theory), we have been able to elucidate crystal structures of high-pressure polymorphs of AgF2. The transition from ambient pressure to an unprecedented nanotubular structure takes place via an intermediate orthorhombic layered structure, which lacks an inversion center. The observed phase transitions are discussed within the broader framework of the fluorite → cotunnite → Ni2In series, which has been seen for other metal difluorides.

Download: